After topping the qualification heats on Friday, James was unable to replicate his near perfect scores finishing with a best total of 38.75 in the ten man final.
Japan's Ayuma Hirano claimed the victory with a score of 95.25 ahead of the USA's Ben Ferguson and Shaun White.
The VIS rider was unable to stick any of his runs, opening with a 19.00, before putting together his best run of 38.75 before closing out with a 16.75.
Fellow Australian Kent Callister finished 23rd overall.
In the women’s event Lillehammer 2016 Youth Olympic silver medallist Emily Arthur put down two solid runs of 58.66 and 60.00 to finish ninth in her qualification heat and an overall placing of 16th.
The women's event was an American clean sweep, with Chloe Kim taking the win ahead of Maddie Mastro and Kelly Clark.
James and his Australian teammates will now turn their attention to the Dew Tour event at Breckenridge which begins on Thursday.
Matt Bartolo
olympics.com.au